How to stop lithium-ion batteries explosion due to thermal runaway?
Thermal runaway is a long standing problem that has bugged large corporations like Tesla, Samsung, and Boeing and small alike.
Boeing’s Dreamliner 787, which Boeing advertised as 20% fuel efficient, was grounded in 2013. In the same year, Tesla’s Model S came under a federal safety investigation after it caught fire at least 3 times. Last year Samsung recalled 2.5 million Galaxy Note 7 smartphone.
For all the three companies, which are top players of their domain, the problem was same – the Lithium-Ion batteries installed in heart of their product as a power source. The lithium-ion batteries installed in Tesla Model S, Dreamliner 787 and Galaxy Note 7 were exploding continuously.
Why does a Lithium ion battery explode unexpectedly?
Lithium ion batteries are the most used type of batteries across several industries but, do you know what makes makes them hazardous? If you’re a researcher working with Li-ion batteries, you would know that one of the major reasons why most of the lithium-ion batteries explode is because of thermal runaway.
What is Thermal Runaway and why it is the leading cause of battery explosions?
In Lithium-ion batteries, cathode and anode are separated by a thin – sometimes 10 microns – polyethylene separator. When this separator ruptures, a short circuit happens which initiates the process called thermal runaway.
Thermal runaway happens usually during charging. The temperature quickly rises to the melting point of the metallic lithium and causes a violent reaction.
Another major reason behind thermal runaway is other microscopic metal particles coming in touch with different parts of the battery (this happens all the time in the battery assembly process), resulting in a short-circuit.
Usually, a mild short circuit can cause an elevated self-discharge and little heat is generated because the discharging energy is very low. But, when enough microscopic metal particles converge on one spot, a major electrical short can develop and a sizable current will flow between the positive and negative plates.
This causes the temperature to rise, leading to a thermal runaway, also referred to ‘venting with flame.’
During a thermal runaway, the high heat of the failing cell can propagate to the next cell, causing it to become thermally unstable as well. In some cases, a chain reaction occurs in which each cell disintegrates at its own timetable.
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Why is Explosion of Li-Ion batteries a major issue for all?
The smartphone in your pocket is powered by a Li-Ion battery. They are one of the most popular types of rechargeable batteries for portable electronics because of their high energy density, tiny memory effect, and low self-discharge.
Beyond consumer electronics, Lithium Ion batteries are popular for military, electric vehicle and aerospace applications. For example, lithium ion batteries have replaced the conventional lead–acid batteries that have been used historically for golf carts and utility vehicles.
The Global Lithium-Ion Battery Market size is expected reach $46.21 billion by 2022, with a CAGR of 10.8% during the period 2016-2022.
For something which has become an integral part of our everyday life at such a fast pace, we would indeed be risking our lives having these batteries around us.
Given their applications, they are not easily replaceable but if the thermal runaway problem could be solved, the balance would restore in paradise.
How can we prevent thermal runaway in lithium ion batteries?
We thought to spend some time and find existing research solutions to this problem.
Our search team did some deep digging and returned with a set of solutions that could solve the thermal runaway problem for the R&D community of this domain. The three solution which we believe can put an end to thermal runaway problem in batteries are listed below –
1. Introducing a Flame Retardant
Thermal runaway often occurs from punctures and improper charging. To counter such fire hazards, the inventors used a thermal fluid which contains a flame retardant.
A flame retardant is a compound that inhibits, suppresses or delays the production of flames or prevents the spread of fire.
Here they have the microencapsulated the flame retardant (usually a bromine compound) in high-density polyethylene and added water and a glycol compound to prepare the thermal fluid used. The glycol compound is used here as “antifreeze” (common glycol compounds used are ethylene glycol, diethylene glycol, and propylene glycol).
Also, the invention is mostly discussed in light of EV batteries. A battery when called upon to power an electric vehicle heats up. Thermal fluid flows through the container and over the modules of the battery.
In the event of an overcharge, or a car accident resulting in a battery puncture, the flame retardant in the thermal fluid acts to reduce the fire hazard. More precisely, bromine compound microcapsules rupture when rupture temperature is reached because of excess heat of the fire. The flame retardant is released from the microcapsules and acts to bring the fire under control.
2. Using Damage initiating Devices
The Regents of the University of California seems to be pretty active in researching how to deal with thermal runaway problem.
In 2006, they filed a patent related to high elastic modulus polymer electrolytes suitable for preventing thermal runaway (US8703310). A different set of inventors has filed this patent (i.e. US’535) in 2013, about mitigating thermal runaway using damage-initiating materials or devices.
More precisely, they have developed a thermal runaway shutdown mechanism that can be triggered either mechanically or thermally (or both), as battery damage happens (i.e., before or shortly after thermal runaway starts) and take care of the problem before it can even begin.
Such predictive or instantaneous countermeasures are especially needed when a battery is subjected to impact or high-pressure (like an accident as I mentioned for the previous patent US’886 as well) and its internal structure damaged, causing internal shorting.
The basic principle on which it operates is – as a mechanical load is applied to the battery, damage initiators can trigger widespread damage or destruction of the electrode so that the internal resistance increases significantly to mitigate thermal runaway even before it can happen.
Here they have talked about two types of damage initiators –
Passive damage initiators
These initiators initiate cracking or voiding in electrodes upon impact, and such cracks and/or voids increase the internal impedance of the electrode and, thus, reduce heat generation associated with possible internal shorting. Such additives are known as cracks or voids initiators (CVIs).
The electrode damages can be caused by debonding or stiffness mismatch of CVI-electrode interfaces, fracture, and rupture of CVI, etc. Examples of passive additives include solid or porous particles, solid or hollow/porous fibers, and tubes, etc. and they can be formed from carbon materials such as graphite, carbon nanotubes, activated carbons, carbon blacks, etc.
Active damage initiator
These initiators can produce a significant volume or shape change upon a mechanical or thermal loading. Active damage initiators can include solid or porous particles, solid or hollow beads, solid or hollow/porous fibers and tubes, etc. Active damage initiators can be formed from shape-memory alloys such as Ni—Ti, Ni—Ti—Pd, Ni—Ti—Pt, etc.
3. Changing the Battery Design for Minimal Impact
According to a patent filed by Tesla, the inventors discussed a battery design that provides a predictable pathway through a portion of the cell (e.g., the cell cap assembly) for the efficient release of the thermal energy that occurs during thermal runaway, thereby reducing the chances of a rupture in an undesirable location.
Furthermore, the design maintains the functionality of the cell cap as the positive terminal of the cell, thereby having minimal impact on the manufacturability and maximum use in a variety of applications.
While searching for solutions, we also found some quality solutions to other problems in LIB domain listed below.
- How to overcome dendrite formation?
- How to increase the life cycle of Lithium ion batteries?
- How to decrease viscosity and increase dispersion efficiency of anode binders?
- How to you can make your LIB operate at high temperature?
If you are facing problems and are seeking solutions, including but not limited to above mentioned, do get in touch. We might be able to put an end to your woes. To give you an example, recently we helped Joe, senior researcher at one of the largest chemical companies in the US, find a solution to temperature resistance problem in acrylate adhesives?
Authored by: Arindam Som, Group Manager, Operations and Vidhi Sharma, Research Analyst, Patent Search